Chemicals and Chemistry
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Chemistry
Researchers from University of Kiel provide details of new studies and findings in the area of chemistry
May 21st, 2010
"Reaction of manganese and iron thiocyanate with pyrimidine in solution at room temperature leads to the formation of the isotypic new ligand-rich 1:2 (1:2 = ratio between metal and ligand) compounds [Mn(NCS)(2)(pyrimidine)(2)](n) (1) and [Fe(NCS)(2)(pyrimidine)(2)](n) (2). Their crystal structures were determined by single crystal X-ray analysis," investigators in Kiel, Germany report. "The metal cations are coordinated by four pyrimidine ligands, which connect them into layers, and two terminal N-bonded thiocyanato anions in a distorted octahedral arrangement. Investigations on their thermal behavior show that the complexes decompose quantitatively into the...
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Source: Chemicals and Chemistry (2010-05-21)
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