Journal of Physics Research
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Chemical Physics
Scientists at Firat University discuss research in chemical physics
January 13th, 2009
According to recent research from Elazig, Turkey, "We present the Born-Oppenheimer dynamics of the depletion reaction NH(a(1)Delta)+H-'- > N(D-2)+H-2 and of the exchange one NH(a(1)Delta)+H-'- > NH'(a(1)Delta)+H, using the real wavepacket and flux methods and an accurate NH2(A (2)A(1)) surface. We report coupled-channel reaction probabilities, cross sections, and rate constants, taking into account Coriolis couplings." "Because the surface is barrierless and strongly bound, probabilities have small centrifugal thresholds and present sharp and large resonances, associated with long-lived collision complexes. Large J's enhance the high-energy reactivity and favor the...
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Source: Journal of Physics Research (2009-01-13)
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